Kirihara and Tachibana
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In the Kantō Tournament, Rikkai Dai faces off against Fudomine. Kirihara plays against 3rd year and Captain Tachibana Kippei in Singles 3. Although Tachibana is a nationally-ranked player, he had locked away his Wild Beast Aura at that point.
Like Kirihara in his Bloodshot or Devil Modes, he used to be a player with more-or-less hidden violent tendencies, although Kirihara's violent play is due to his snapping into different states of mind due to pressure or physical injury; Tachibana's violent play appeared to be conscious.
Tachibana ultimately loses 6-1, after toying with Kirihara for one game and taunting him about the time limit Kirihara had set himself for the match. Kirihara entered Bloodshot and proceeded to win the next six games, aiming the ball at his head and stomach as he did so. It should be noted that this is apparently the first time Kirihara had entered Bloodshot in a while - possibly since his defeat at the hands of the "Three Demons" of Rikkai Dai, when he was in his first year and before he became a Regular.
Jackal Kuwahara, his teammate, mentions that he was surprised at Kirihara's increased speed and power in his Bloodshot mode when he played against Tachibana, as he thought Kirihara had been playing 'seriously' up until that match; it can be inferred that Jackal had not seen Kirihara go Bloodshot before that time.